Synthesis and Characterisation of the First Oxazoline Coordination Compounds Containing the Cu(F6acac)2 Unit: X-ray Diffraction Studies of Cu(kappa2-O,O'-F6acac)2(kappa1-N-Meox) and Cu(kappa2-O,O'-F6acac)2(kappa1-N-Etox)

Authors

  • Paras N. Yadav Central Department of Chemistry, Tribhuvan University, Kirtipur, Kathmandu
  • Tosha M. Barclay Department of Chemistry, Lone Star College-North Harris Campus, 2700 W.W. Thorne Drive, Houston
  • Robert A. Gossage Dept. of Chemistry & Biology, Ryerson University, 350 Victoria Street, Toronto ON M5B 2K3

DOI:

https://doi.org/10.3126/jncs.v28i0.8059

Keywords:

Oxazoline, Copper, Hexafluoroacetylacetonato, Coordination complex, Oxazole

Abstract

The synthesis and characterisation (elemental analysis, IR, X-ray diffraction) of the first two oxazoline coordination compounds of Cu(F6acac)2 are described. Both of these complexes are five-coordinate mononuclear formally Cu(II) materials with a slightly distorted square pyramidal coordination motif around the metal centre. The structures are compared and contrasted to other N-donor complexes of Cu(F6acac)2.

DOI: http://dx.doi.org/10.3126/jncs.v28i0.8059

Journal of Nepal Chemical Society
Vol.28, 2011
Page: 54-58
Uploaded date: May 7, 2013

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Published

2013-05-07

How to Cite

Yadav, P. N., Barclay, T. M., & Gossage, R. A. (2013). Synthesis and Characterisation of the First Oxazoline Coordination Compounds Containing the Cu(F6acac)2 Unit: X-ray Diffraction Studies of Cu(kappa2-O,O’-F6acac)2(kappa1-N-Meox) and Cu(kappa2-O,O’-F6acac)2(kappa1-N-Etox). Journal of Nepal Chemical Society, 28, 54–58. https://doi.org/10.3126/jncs.v28i0.8059

Issue

Vol. 28 (2011)

Section

Articles

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© Journal of Nepal Chemical Society