Synthesis, characterisation and reactions of cationic complexes of Arylantimony (III) chlorides ArnSbCl3-n with perchlorate and tetrafluoroborate anions

Authors

  • Ram Nath Prasad Yadav Department of Chemistry, Tribhuvan University, Thakur Ram Multiple Campus, Birganj

DOI:

https://doi.org/10.3126/ijasbt.v1i2.8204

Keywords:

Arylantimony(III) chloride, Cationic complex, IR spectra, Elemental analysis, Molecular weight measurement, Perchlorate, Tetrafluoroborate

Abstract

Several hitherto unreported cationic complexes of the general formula [Ar2SbL][Y] and [ArSbL2][Y]2 [ Where, Ar  =  C6H5, L =  α-Picoline, Pyridine, Ph3AsO, hexamethyl phosphoramide (HMPA), thiourea (TU) and Y = ClO4− BF4− ] have been synthesized and characterized by solid state IR, 1H NMR, elemental analysis, conductance and molecular weight measurements. The physico-chemical data, cations [Ar2SbL]+1 and[ArSbL2]+2  are assigned a pyramidal structure.

DOI: http://dx.doi.org/10.3126/ijasbt.v1i2.8204

Int J Appl Sci Biotechnol, Vol. 1(2): 42-49

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Published

2013-06-15

How to Cite

Yadav, R. N. P. (2013). Synthesis, characterisation and reactions of cationic complexes of Arylantimony (III) chlorides ArnSbCl3-n with perchlorate and tetrafluoroborate anions. International Journal of Applied Sciences and Biotechnology, 1(2), 42–48. https://doi.org/10.3126/ijasbt.v1i2.8204

Issue

Vol. 1 No. 2 (2013)

Section

Research Articles: Biological Sciences